A facile route to the production of polymeric nanofibrous aerogels for environmentally sustainable applications

Abstract: Mesoporous polymeric aerogels with high compressibility and durability have drawn great attentions due to their environmentally sustainable applications. However, it is still challenging to develop polymeric aerogels in a simple, low-cost and mass produced way. Here, we report a strategy to create high porosity polymeric nanofibrous aerogel (referred to as NFA) by direct freeze-drying of the poly (vinylalcohol-co-ethylene) (PVA-co-PE) nanofibrous suspension. It is noteworthy that this process is free of gelation and any solvent exchange. Also, the PVA-co-PE nanofibers are mass-produced from our production line based on a high throughput Melt-Extrusion-Phase-Separation technique. Additionally, the network of the NFA aerogels can be tuned by the host-guest assembly of the nanofibers and the foreign PVA nano- lamellae from disordered/ordered cellular to leaf-like structure. Further modification of the NFA by gaseous methyltrichlorosilane (MTS) leads to covalently bonded siloxane nanoparticles formed on the surface, thereby facilely realizing the nanofibrous aerogel from hydrophilic to hydrophobic as well as achieving excellent resilience. The corresponding hydrophobic aerogel (designated as HNFA) possesses a slightly larger density of 11.1 mg cm^-3 with almost unchanged porosity of 99% and meso-macroporous pores of 5-100 nm compared with the NFA (8.3 mg cm^-3). They have been demonstrated as good thermal insulator (0.033-0.044 Wm^-1K^-1), high-performance air filter (99.2% filtration efficiency with 64 Pa pressure drop), organic pollutants absorbents (2500-5329% weight gain) and continuous water/oil separator. Therefore, this study opens up a new approach for simple and large-scale preparation of polymeric aerogels for versatile applications.

Qiongzhen Liu, et al. A facile route to the production of polymeric nanofibrous aerogels for environmentally sustainable applications[J]. Journal of Materials Chemistry A. 2018. 6. 3692-3704.